Uploaded April 2022 | Updated September 2026, 2 weeks ago
A supersaturated solution contains more than the maximum amount of solute than is capable of being dissolved at the current temperature. I dissolved sodium acetate in hot water, then allowed it to cool. At this lower temperature, it’s an inherently unstable solution, so the only thing I needed to do to get a precipitation reaction to start was to add a few crystals of solid sodium acetate.
#chemistry #chemistryeducation #chemistrylab
A supersaturated solution contains more than the maximum amount of solute than is capable of being dissolved at the current temperature. I dissolved sodium acetate in hot water, then allowed it to cool. At this lower temperature, it’s an inherently unstable solution, so the only thing I needed to do to get a precipitation reaction to start was to add a few crystals of solid sodium acetate.
#chemistry #chemistryeducation #chemistrylab


![SN2 Trap: Why (R) Doesnt Always Invert to (S)
Think SN2 always inverts R/S configuration? Dont fall for the (R) to (R) trap on your midterm! If youve been taught the Golden Rule that SN2 must flip between R/S, this video is required viewing.
Were dissecting a textbook lie utilizing a 1970s breakthrough from the H.C. Brown lab. Ill show you exactly how an (R) reactant can produce an (R) product through a perfectly standard SN2 mechanism, WITHOUT breaking a single rule.
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What youll master in this gotcha question breakdown:
• The CIP Trap: Why (R) to (R) isnt a mechanism failure, but a priority change.
• Super-Hydride Logic: Dissection lithium triethylborohydride (LiEt3BH) to see why its the surgical strike of nucleophiles.
• The Spatial Literacy Test: Using 3D molecular models to see the backside attack when the 2D drawings fail you.
0:00 The 5-Point SN2 Chirality Trap
0:23 Tiebreakers: Assigning Priorities to the Reactant
1:00 The Hand Rule: Confirming the (R) Configuration
1:26 Is Super-Hydride too bulky for SN2?
1:48 [SOURCE] Krishnamurthy & Brown Paper (1982)
2:08 3D Model Walkthrough: Geometry of the Nucleophile
2:54 The Mechanism: Concerted Backside Attack
3:55 The Umbrella Inversion vs. Configuration
4:30 Re-evaluating Priorities for the Product
4:56 The Hand Rule: Why the Product is (R)
5:10 The Verdict: Why (R) stayed (R)
5:23 Pro-Tip: How to assign R/S in seconds
📖The Research (Primary Source for LiEt3BH): Selective reductions. 31. Lithium triethylborohydride as an exceptionally powerful nucleophile. A new and remarkably rapid methodology for the hydrogenolysis of alkyl halides under mild conditions
S. Krishnamurthy and Herbert C. Brown
The Journal of Organic Chemistry 1983 48 (18), 3085-3091
DOI: 10.1021/jo00166a031
https://pubs.acs.org/doi/pdf/10.1021/jo00166a031
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Citations:
Paula Yurkanis Bruice, Organic Chemistry 8th ed
https://openstax.org/details/books/organic-chemistry
https://openstax.org/details/books/chemistry-2e
Music: https://youtu.be/lL6AsbG07xY SN2 Trap: Why (R) Doesnt Always Invert to (S)](https://i.ytimg.com/vi/IHSRGx_GlZA/mqdefault.jpg)







