Brook Rearrangement Mechanism | Organic Chemistry @OrganicMechanismsChannel

Uploaded March 2022 | Updated September 2026, 1 week ago

Rearrangement of α-silyl oxyanions to α-silyloxy carbanions via a reversible process involving a pentacoordinate silicon intermediate is known as the [1,2]- Brook rearrangement, or [1,2]-silyl migration.

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